Sex pheromone biosynthesis in the female olive fruit-fly. Double labelling from [18O2]-dioxygen into 1,7-dioxaspiro[5.5]undecaneView Altmetrics View AltmetricsTools Fletcher, M. T., Mazomenos, B. E., Georgakopoulos, J. H., Konstantopoulou, M. A., Wood, B. J., De Voss, J. J. and Kitching, W. (2002) Sex pheromone biosynthesis in the female olive fruit-fly. Double labelling from [18O2]-dioxygen into 1,7-dioxaspiro[5.5]undecane. Chemical Communications (12). pp. 1302-1303. ISSN 1364-548X Full text not currently attached. Access may be available via the Publisher's website or OpenAccess link. Article Link: https://doi.org/10.1039/B202697J AbstractThe demonstration that both oxygen atoms of 1,7-dioxaspiro[5.5]undecane (1), the sex-pheromone of the female olive fly, originate from dioxygen, strongly implicates monooxygenase mediated processes in assembly of (1), and reveals unexpected complexity in the formation of its nine-carbon precursor.
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